READ ME This text describes the data presented in the paper: <[Ru(phen)2dppz]2+ Luminescence Reveals Nanoscale Variation of Polarity in the Cyclodextrin Cavity> ======================== Introductory information ======================== Files included in the data deposit: Experimental data and least squares lifetime fits for single photo counting experiments Folder: Luminescence Lifetime Data and Analysis 1)Λ-Ru(phen)2dppz Bi-Exp Lifetime .xlsx 2)Λ-Ru(phen)2dppz Tri-Exp Lifetime.xlsx 3)∆-Ru(bpy)3 Emission Lifetime.xlsx 4)∆-Ru(phen)2dppz Bi-Exp Lifetime.xlsx 5)∆-Ru(phen)2dppz Tri-Exp Lifetime.xlsx 6)∆-Ru(phen)3 Emission Lifetime.xlsx Absorption and emission spectral titrations of metal complex with phosphorylated beta-cyclodextrin Folder: [Ru(phen)2dppz]2+ Titrations with Cyclodextrins 1)Ru(phen)2dppz Absorption_run 3.xlsx 2)Ru(phen)2dppz Emission_run 3.xlsx Key words used to describe the data: Emission, excited state lifetimes, absorption ========================== Methodological information ========================== A brief method description ñ what the data is, how and why it was collected or created, and how it was processed: Absorption and emission data to deermine binding constants and environmental information Instruments, hardware and software used: Varian-Cary 150-bio for absorption SPEX fluorolog for emisison, Home-built instrument for fluorescence lifetimes (Durham University). Date(s) of data collection: 2003-2014 Geographic coverage of data: UK Data validation (how was the data checked, proofed and cleaned): baseline subtractions to zero the spectra. Least squares fits in Excel using Solver to analyse lifetimes Overview of secondary data, if used: N/A ========================= Data-specific information ========================= Definitions of names, labels, acronyms or specialist terminology uses for variables, records and their values: tau - emission lifetime Explanation of weighting and grossing variables: N/A Outline any missing data: N/A ======= Contact ======= Please contact rdm@ncl.ac.uk for further information