Ruthenium Assemblies for CO2 Reduction and H2 Generation: Time Resolved Infrared Spectroscopy, Spectroelectrochemistry and a Photocatalysis Study in Solution and on NiO

Posted on 09.11.2021 - 14:15 by Joshua Karlsson

This data collection contains raw data for the manuscript titled "Ruthenium Assemblies for CO2 Reduction and H2 Generation: Time Resolved Infrared Spectroscopy, Spectroelectrochemistry and a Photocatalysis Study in Solution and on NiO". Raw date pertains to photoelectrocatalysis experiments where the molecular photocatalysts were immobilised on NiO thin films, and exposed to light in a three-electrode cell with an applied external bias. Details of the experimental setup are in the paper.


Data here is in three sections: 1. gas chromatography data, 2. UV-visible absorption results and 3. electrochemistry data from the three-electrode cell setup.


In general the filenames for the data contain sufficient information, together with the manuscript to identify the experiment and the system used.


From the manuscript the compounds are identified as per the titles below, corresponding to file identifies in this folder:


Ru = Ru(dceb)bpt

Ru-Re = Ru(dceb)bptRe(CO)3Cl

Ru-Pt = Ru(dceb)2bptPtI2


For the electrochemical measurements the file names contain the pH conditions and the scan rate where appropriate, all which can be cross-referenced against the manuscript. Within the raw data the data is appropriately labelled so that one can determine what bias the experiment was run at, where a chronoamperometry (chronoamp) experiment was performed.

CITE THIS COLLECTION

Karlsson, Joshua (2021): Ruthenium Assemblies for CO2 Reduction and H2 Generation: Time Resolved Infrared Spectroscopy, Spectroelectrochemistry and a Photocatalysis Study in Solution and on NiO. Newcastle University. Collection. https://doi.org/10.25405/data.ncl.c.5696935.v1
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FUNDING

The North East Centre for Energy Materials EP/R021503/1, Sustainable Energy Authority of Ireland under the SEAI National Energy Research, Development & Demonstration Funding Programme 2019, Grant number 18/RDD/282, and Project 785 “HYLANTIC” (EAPA_204/2016), which is co-financed by 786 the European Regional Development Found in the framework 787 of the Interreg Atlantic programme.

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