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README_template.txt (1.18 kB)

DATASET

PEGA_EtOH_PdPolyacrylatePaper.xlsx (10.51 MB)

DATASET

PhAc_Alcohols_Pdpolyac paper.xlsx (9.43 MB)

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READ ME Novakovic.docx (14.31 kB)

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Data description.docx (11.82 kB)

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PhAc Pd(OAc)2 -paper.xlsx (6.83 MB)

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Pd-catalysed oscillatory carbonylation reactions: solvent, substrate, catalyst

dataset

posted on 2019-01-01, 00:00 authored by K Novakovic, J Parker

Data demonstrate that pH oscillations in carbonylation reactions have the potential to occur in a broad range of aliphatic alcohol solutions when using either a small molecule substrate (phenylacetylene) or a polymeric substrate (pegylated alkyne) with either a small molecule catalyst (Pd-diacetate) or a non-leaching polymeric catalyst (Pd-polyacrylate). The alcohols studied are methanol, ethanol, 1-propanol, 1-butanol and 1-hexanol.