ns laser flash photolysis of KMoSn[BOD] in MeCN
Elizabeth Gibson
10.25405/data.ncl.12133191.v1
https://data.ncl.ac.uk/articles/dataset/ns_laser_flash_photolysis_of_KMoSn_BOD_in_MeCN/12133191
<p>Transient absorption spectroscopy was
performed on acetonitrile solution samples of the bodipy hybrid TBA-KMoSn[BOD]
with an OD 0.25 to 0.9 AU, in a 1 mm pathlength quartz cuvette.
The samples were purged with N<sub>2</sub> before each measurement. For
recording the ns-μs dynamics of the Mo system an
externally triggered Q-switched Nd: YVO<sub>4</sub> laser (Advanced Optical
Technology, 532 nm, 1 ns pulses, intensity of ~600 μW) was used as a pump source, while the ordinary femtosecond detection, photodiode
array coupled to a spectrograph (Pascher Instruments), with
supercontinuum probe was used to record the transient changes in the
absorption.<br></p>
<p> </p>
<p>The filenames refer to
the sample and addition of aliquots of trifluoroacetic acid (numbers refer to
molar equivalents of acid).</p>
2020-04-20 09:08:11
Transient absorption measurement
Polyoxometalate Clusters Covalently Attached
BODIPY chromophores
Optical Properties of Materials